Homogeneous nucleation rates for water

We have investigated homogeneous nucleation of water droplets in the vapor phase. Nucleation in water vapor has been previously studied a number of times using various experimental techniques. The nucleation pulse technique used here allows accurate measurements of homogeneous nucleation rates J vs...

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Veröffentlicht in:The Journal of chemical physics 1993-09, Vol.99 (6), p.4680-4692
Hauptverfasser: VIISANEN, Y, STREY, R, REISS, H
Format: Artikel
Sprache:eng
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Zusammenfassung:We have investigated homogeneous nucleation of water droplets in the vapor phase. Nucleation in water vapor has been previously studied a number of times using various experimental techniques. The nucleation pulse technique used here allows accurate measurements of homogeneous nucleation rates J vs supersaturation S in the range from 105 to 109 cm−3 s−1. The advance reported here consists of the fact that the J–S curves are measured at a selectable constant temperature. We determined the nucleation rates in supersaturated water vapor mixed with various carrier gases as functions of supersaturation and temperature (217
ISSN:0021-9606
1089-7690
DOI:10.1063/1.466066