Random sequential multilayer deposition of different-sized k mers on a one dimensional infinite substrate

Kinetics of random sequential, irreversible multilayer deposition of macromolecules of two different sizes on a one dimensional infinite lattice is analyzed at the mean field level. A formal solution for the corresponding rate equation is obtained. The Jamming limits and the distribution of gaps of...

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Veröffentlicht in:The Journal of chemical physics 1993-12, Vol.99 (11), p.8897-8907
Hauptverfasser: BIPLAB BHATTACHARJEE, RANGARAJAN, S. K
Format: Artikel
Sprache:eng
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Zusammenfassung:Kinetics of random sequential, irreversible multilayer deposition of macromolecules of two different sizes on a one dimensional infinite lattice is analyzed at the mean field level. A formal solution for the corresponding rate equation is obtained. The Jamming limits and the distribution of gaps of exact sizes are discussed. In the absence of screening, the jamming limits are shown to be the same for all the layers. A detailed analysis for the components differing by one monomer unit is presented. The small and large time behaviors and the dependence of the individual jamming limits of the k mers and (k−1) mers on k and the rate parameters are analyzed.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.465558