Wave packet dynamics of the HgI2 photodissociation reaction in solution

Using femtosecond absorption spectroscopy, the photodissociation dynamics of HgI2 in solution were investigated. Upon photolysis, the HgI fragment is formed in a coherent superposition of its vibrational states. Solvent dependence of the wave packet motion is evidenced by the different results for e...

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Veröffentlicht in:	The Journal of chemical physics 1993-11, Vol.99 (9), p.7273-7276
Hauptverfasser:	PUGLIANO, N, PALIT, D. K, SZARKA, A. Z, HOCHSTRASSER, R. M
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Exact sciences and technology General and physical chemistry Photochemistry Physical chemistry of induced reactions (with radiations, particles and ultrasonics)
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	Using femtosecond absorption spectroscopy, the photodissociation dynamics of HgI2 in solution were investigated. Upon photolysis, the HgI fragment is formed in a coherent superposition of its vibrational states. Solvent dependence of the wave packet motion is evidenced by the different results for ethanol and DMSO and between solution and gas phase.
ISSN:	0021-9606 1089-7690
DOI:	10.1063/1.465422