Crossed beam studies of four-atom reactions : the dynamics of OH+CO

Crossed beam studies of four-atom reactions : the dynamics of OH+CO

The angular and velocity distribution of CO2 product from the reaction OH+CO at 14.1 kcal/mole collision energy has been obtained in a crossed molecular beam study. The reaction is found to proceed through an osculating HOCO complex living about one rotational period. About 65% of the available ener...

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Veröffentlicht in:The Journal of chemical physics 1993-05, Vol.98 (10), p.8341-8344
Hauptverfasser: ALAGIA, M, BALUCANI, N, CASAVECCHIA, P, STRANGES, D, VOLPI, G. G
Format: Artikel
Sprache:eng
Schlagworte:
Atomic and molecular collision processes and interactions
Atomic and molecular physics
Exact sciences and technology
Physics
Scattering of atoms, molecules and ions
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Zusammenfassung:The angular and velocity distribution of CO2 product from the reaction OH+CO at 14.1 kcal/mole collision energy has been obtained in a crossed molecular beam study. The reaction is found to proceed through an osculating HOCO complex living about one rotational period. About 65% of the available energy goes into product translation.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.464540