Thermodynamic and stochastic theory for nonideal systems far from equilibrium

Thermodynamic and stochastic theory for nonideal systems far from equilibrium

The thermodynamic and stochastic theory of nonlinear chemical kinetics systems, possibly with multiple stable stationary states, is extended to nonideal species, either nonideal gases or nonideal solutions. The Brönsted theory of the kinetics of nonideal species is chosen for explicit formulation of...

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Veröffentlicht in:The Journal of chemical physics 1993-06, Vol.98 (12), p.9765-9770
Hauptverfasser: ROSS, J, XIAOLIN CHU
Format: Artikel
Sprache:eng
Schlagworte:
Chemical thermodynamics
Chemistry
Exact sciences and technology
General and physical chemistry
General. Theory
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Beschreibung
Zusammenfassung:The thermodynamic and stochastic theory of nonlinear chemical kinetics systems, possibly with multiple stable stationary states, is extended to nonideal species, either nonideal gases or nonideal solutions. The Brönsted theory of the kinetics of nonideal species is chosen for explicit formulation of this extension, but the development is similar for other choices.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.464355