Ion rotational distributions for near-threshold photoionization of H2O

Ion rotational distributions for near-threshold photoionization of H2O

Ion rotational distributions for single-photon VUV photoionization of the 1b1 orbital of the X̃ 1A1 ground state of the jet-cooled water are reported. These spectra reveal significant type a transitions which are seen to arise from odd angular momentum components of the photoelectron matrix element....

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Veröffentlicht in:The Journal of chemical physics 1992-05, Vol.96 (10), p.7848-7851
Hauptverfasser: LEE, M.-T, WANG, K, MCKOY, V, TONKYN, R. G, WIEDMANN, R. T, GRANT, E. R, WHITE, M. G
Format: Artikel
Sprache:eng
Schlagworte:
Atomic and molecular physics
Exact sciences and technology
Molecular properties and interactions with photons
Photon interactions with molecules
Physics
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Zusammenfassung:Ion rotational distributions for single-photon VUV photoionization of the 1b1 orbital of the X̃ 1A1 ground state of the jet-cooled water are reported. These spectra reveal significant type a transitions which are seen to arise from odd angular momentum components of the photoelectron matrix element. The resulting photoionization dynamics are quite nonatomic-like.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.462381