Dielectric study of percolation in an oil-continuous microemulsion

Measurements of the electrical conductivity and the complex permittivity near a percolation threshold in the ternary microemulsion system composed of water, iso-octane, and AOT are reported. It is shown that the electrical conductivity, which implies charge transfer process, is well described by a d...

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Veröffentlicht in:The Journal of chemical physics 1991-05, Vol.94 (10), p.6879-6886
Hauptverfasser: PONTON, A, BOSE, T. K, DELBOS, G
Format: Artikel
Sprache:eng
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Zusammenfassung:Measurements of the electrical conductivity and the complex permittivity near a percolation threshold in the ternary microemulsion system composed of water, iso-octane, and AOT are reported. It is shown that the electrical conductivity, which implies charge transfer process, is well described by a dynamic percolation model. The frequency dependence of the dielectric constant and the behavior of the relaxation frequency are also found to be in close agreement with the scaling power laws of the dynamic percolation model.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.460268