Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites
A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transitio...
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| Veröffentlicht in: | The Journal of chemical physics 1990-02, Vol.92 (4), p.2646-2649 |
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| container_title | The Journal of chemical physics |
| container_volume | 92 |
| creator | HUCKABY, D. A BLUM, L |
| description | A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transition when the stickiness parameter λ, singlet wall density ρ01(0), and pair correlation function g02(d) satisfy λρ01(0)[g02(d)]3=1. If d |
| doi_str_mv | 10.1063/1.457959 |
| format | Article |
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In this case there is a second order phase transition between an ordered 7/8 × 7/8 phase and a disordered one.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.457959</identifier><identifier>CODEN: JCPSA6</identifier><language>eng</language><publisher>Woodbury, NY: American Institute of Physics</publisher><subject>Chemistry ; Exact sciences and technology ; General and physical chemistry ; Solid-gas interface ; Surface physical chemistry</subject><ispartof>The Journal of chemical physics, 1990-02, Vol.92 (4), p.2646-2649</ispartof><rights>1993 INIST-CNRS</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c256t-f4a25a6e89b28b3f6920761868ca27188d7e8560e3890f9d5c4deace481346163</citedby><cites>FETCH-LOGICAL-c256t-f4a25a6e89b28b3f6920761868ca27188d7e8560e3890f9d5c4deace481346163</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids><backlink>$$Uhttp://pascal-francis.inist.fr/vibad/index.php?action=getRecordDetail&idt=4340492$$DView record in Pascal Francis$$Hfree_for_read</backlink></links><search><creatorcontrib>HUCKABY, D. A</creatorcontrib><creatorcontrib>BLUM, L</creatorcontrib><title>Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites</title><title>The Journal of chemical physics</title><description>A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transition when the stickiness parameter λ, singlet wall density ρ01(0), and pair correlation function g02(d) satisfy λρ01(0)[g02(d)]3=1. If d<σ< 7/8 d, and further neighbors do not interact, the model is equivalent to the hard hexagon model solved by Baxter. In this case there is a second order phase transition between an ordered 7/8 × 7/8 phase and a disordered one.</description><subject>Chemistry</subject><subject>Exact sciences and technology</subject><subject>General and physical chemistry</subject><subject>Solid-gas interface</subject><subject>Surface physical chemistry</subject><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1990</creationdate><recordtype>article</recordtype><recordid>eNo9kMFKAzEURYMoWKvgJ2Thws3Ul0wmkyyl1CoU3OjKxfCaSTQ6TkpeCvbvbam4upfL4S4OY9cCZgJ0fSdmqmltY0_YRICxVastnLIJgBSV1aDP2QXRJwCIVqoJe1v8oCs8e9oOhXhImZcPz7GnlDclppGnwJH3fiTPw7CNPU9jSfup5Ijj-3bAzAcsJTp_QGlfvnacYvF0yc4CDuSv_nLKXh8WL_PHavW8fJrfryonG12qoFA2qL2xa2nWddBWQquF0cahbIUxfetNo8HXxkKwfeNU79F5ZUSttND1lN0ef11ORNmHbpPjN-ZdJ6A7SOlEd5SyR2-O6AbJ4RAyji7SP69qBcrK-hfu6WBs</recordid><startdate>19900215</startdate><enddate>19900215</enddate><creator>HUCKABY, D. 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A</au><au>BLUM, L</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites</atitle><jtitle>The Journal of chemical physics</jtitle><date>1990-02-15</date><risdate>1990</risdate><volume>92</volume><issue>4</issue><spage>2646</spage><epage>2649</epage><pages>2646-2649</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><coden>JCPSA6</coden><abstract>A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transition when the stickiness parameter λ, singlet wall density ρ01(0), and pair correlation function g02(d) satisfy λρ01(0)[g02(d)]3=1. If d<σ< 7/8 d, and further neighbors do not interact, the model is equivalent to the hard hexagon model solved by Baxter. In this case there is a second order phase transition between an ordered 7/8 × 7/8 phase and a disordered one.</abstract><cop>Woodbury, NY</cop><pub>American Institute of Physics</pub><doi>10.1063/1.457959</doi><tpages>4</tpages></addata></record> |
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| ispartof | The Journal of chemical physics, 1990-02, Vol.92 (4), p.2646-2649 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_457959 |
| source | AIP Digital Archive |
| subjects | Chemistry Exact sciences and technology General and physical chemistry Solid-gas interface Surface physical chemistry |
| title | Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites |
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