Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites

A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transitio...

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Veröffentlicht in:The Journal of chemical physics 1990-02, Vol.92 (4), p.2646-2649
Hauptverfasser: HUCKABY, D. A, BLUM, L
Format: Artikel
Sprache:eng
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Zusammenfassung:A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transition when the stickiness parameter λ, singlet wall density ρ01(0), and pair correlation function g02(d) satisfy λρ01(0)[g02(d)]3=1. If d
ISSN:0021-9606
1089-7690
DOI:10.1063/1.457959