Exact results for the adsorption of a dense fluid onto a triangular lattice of sticky sites
A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transitio...
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Veröffentlicht in: | The Journal of chemical physics 1990-02, Vol.92 (4), p.2646-2649 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
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Online-Zugang: | Volltext |
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Zusammenfassung: | A discussion of exact results for the interface between a dense fluid of molecules with a spherical hard core of diameter σ and a triangular lattice of sticky sites with spacing d on a wall with hard repulsive potential is given. When σ≤d and first neighbors attract, there is a first order transition when the stickiness parameter λ, singlet wall density ρ01(0), and pair correlation function g02(d) satisfy λρ01(0)[g02(d)]3=1. If d |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.457959 |