The permanent electric dipole moment of iron monoxide

The Stark effect of the R(2), Q(2) and P(3) lines of the Ω′=2−X 5 Δ2 subband of the ‘‘orange’’ system of iron monoxide at 5919 Å has been measured. Values for the permanent electric dipole moments μ of 4.7±0.2 and 2.6±0.2 D for the ground and excited electronic states, respectively, were derived fro...

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Veröffentlicht in:	The Journal of chemical physics 1989-05, Vol.90 (10), p.5360-5363
Hauptverfasser:	STEIMLE, T. C, NACHMAN, D. F, SHIRLEY, J. E, MERER, A. J
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic and molecular physics Electric and magnetic moments (and derivatives), polarizability and magnetic susceptibility Exact sciences and technology Molecular properties and interactions with photons Physics Properties of molecules and molecular ions
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Beschreibung
Zusammenfassung:	The Stark effect of the R(2), Q(2) and P(3) lines of the Ω′=2−X 5 Δ2 subband of the ‘‘orange’’ system of iron monoxide at 5919 Å has been measured. Values for the permanent electric dipole moments μ of 4.7±0.2 and 2.6±0.2 D for the ground and excited electronic states, respectively, were derived from the analysis of the Stark shift. The results are discussed in terms of the various bonding models and compared with theoretical estimates.
ISSN:	0021-9606 1089-7690
DOI:	10.1063/1.456442