Mean field theory of nematic order for grafted rods
We consider rod-like polymers which are grafted on a flat surface, such that the grafting sites are mobile. A liquid interface supporting a monolayer of amphiphilic copolymers consisting of rod-like and coil-like parts may realize this model. Using the Onsager approach we find that alignment increas...
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Veröffentlicht in: | The Journal of chemical physics 1987-06, Vol.86 (11), p.6550-6555 |
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Hauptverfasser: | , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | We consider rod-like polymers which are grafted on a flat surface, such that the grafting sites are mobile. A liquid interface supporting a monolayer of amphiphilic copolymers consisting of rod-like and coil-like parts may realize this model. Using the Onsager approach we find that alignment increases with surface concentration in a continuous fashion. We present diagrams of surface pressure and of nematic order parameter vs surface concentration. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.452397 |