An optimized random phase approximation for the dynamics of tunneling systems in condensed phases

We derive an optimized random phase approximation from an expansion of the free energy in terms of the generating functional. We apply the theory to a quantum mechanical tunneling system coupled to a Gaussian bath. The theory reproduces both short-time behavior and long-time averages of (real time)...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1985-01, Vol.83 (2), p.668-673
Hauptverfasser: BEHRMAN, E. C, JONGEWARD, G. A, WOLYNES, P. G
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:We derive an optimized random phase approximation from an expansion of the free energy in terms of the generating functional. We apply the theory to a quantum mechanical tunneling system coupled to a Gaussian bath. The theory reproduces both short-time behavior and long-time averages of (real time) correlation functions, and compares favorably with both nonoptimized RPA and the cumulant expansion.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.449535