ESR spectrum of ClO trapped in KClO4

ESR spectrum of ClO trapped in KClO4

The ESR spectrum of a paramagnetic defect produced in solid KClO4 by x irradiation at 26 K is attributed to the radical ClO since the magnetic hyperfine tensor and the nuclear quadrupole tensor of the defect are both satisfactorily accounted for in terms of the hyperfine and quadrupole constants of...

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Veröffentlicht in:The Journal of chemical physics 1985-11, Vol.83 (9), p.4308-4310
1. Verfasser: BYBERG, J. R
Format: Artikel
Sprache:eng
Schlagworte:
Condensed matter: electronic structure, electrical, magnetic, and optical properties
Electron paramagnetic resonance and relaxation
Exact sciences and technology
Free radicals
Magnetic resonances and relaxations in condensed matter, mössbauer effect
Physics
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Zusammenfassung:The ESR spectrum of a paramagnetic defect produced in solid KClO4 by x irradiation at 26 K is attributed to the radical ClO since the magnetic hyperfine tensor and the nuclear quadrupole tensor of the defect are both satisfactorily accounted for in terms of the hyperfine and quadrupole constants of gaseous ClO combined with a crystal-field representation of the influence of the solid matrix.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.449043