Infrared studies of autoionization of thin films of dinitrogen tetroxide

The autoionization of dinitrogen tetroxide to form nitrosonium nitrate in thin films at 150–200 K has been studied using infrared absorption spectroscopy. It is found that at these temperatures and low pressure the process is intramolecular, involving only one of two isomers of the nitrite form (ONO...

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Veröffentlicht in:	The Journal of chemical physics 1985-01, Vol.82 (9), p.4389-4390
Hauptverfasser:	JONES, L. H, SWANSON, B. I, AGNEW, S. F
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Colloidal state and disperse state Exact sciences and technology General and physical chemistry Physical and chemical studies. Granulometry. Electrokinetic phenomena
Online-Zugang:	Volltext
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Beschreibung
Zusammenfassung:	The autoionization of dinitrogen tetroxide to form nitrosonium nitrate in thin films at 150–200 K has been studied using infrared absorption spectroscopy. It is found that at these temperatures and low pressure the process is intramolecular, involving only one of two isomers of the nitrite form (ONONO2). (AIP)
ISSN:	0021-9606 1089-7690
DOI:	10.1063/1.448807