Temperature dependency of the affinity decay rate

Temperature dependency of the affinity decay rate

The temperature dependency of the affinity decay rate of the reacting system was found to be analogous to the temperature dependency of the Helmholtz function of the equilibrium system. Consequently, standard-state internal energies could be computed from the kinetic data and were found to be compar...

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Veröffentlicht in:The Journal of chemical physics 1984-01, Vol.80 (8), p.3640-3643
1. Verfasser: GARFINKLE, M
Format: Artikel
Sprache:eng
Schlagworte:
Chemical thermodynamics
Chemistry
Elements, mineral and organic compounds
Exact sciences and technology
General and physical chemistry
General. Theory
Metals and alloys
Mixtures
Thermodynamic properties
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Zusammenfassung:The temperature dependency of the affinity decay rate of the reacting system was found to be analogous to the temperature dependency of the Helmholtz function of the equilibrium system. Consequently, standard-state internal energies could be computed from the kinetic data and were found to be comparable to experimental internal energies.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.447185