Rate coefficients at 300 K for the vibrational energy transfer reactions from N2( v =1) to O+2( v =0) and NO+( v =0)
Rate coefficients for the reactions N2(v=1)+O+2 (v=0)→N2(v=0)+O+2 (v=1) and N2(v=1)+NO+(v=0)→N2(v=0)+NO+(v=1) have been measured in a SIFT/flowing afterglow system at 300 K, the first measurements of thermal energy vibrational transfer from neutrals to ions. The values are k=1×10−12 and
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| Veröffentlicht in: | The Journal of chemical physics 1984-06, Vol.80 (12), p.6095-6098 |
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| container_issue | 12 |
| container_start_page | 6095 |
| container_title | The Journal of chemical physics |
| container_volume | 80 |
| creator | Ferguson, E. E. Adams, N. G. Smith, D. Alge, E. |
| description | Rate coefficients for the reactions N2(v=1)+O+2 (v=0)→N2(v=0)+O+2 (v=1) and N2(v=1)+NO+(v=0)→N2(v=0)+NO+(v=1) have been measured in a SIFT/flowing afterglow system at 300 K, the first measurements of thermal energy vibrational transfer from neutrals to ions. The values are k=1×10−12 and |
| doi_str_mv | 10.1063/1.446709 |
| format | Article |
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The NO+ result establishes that the efficient quenching of NO+(v=1) by N2 is not a resonant V→V process as was previously assumed.</description><identifier>ISSN: 0021-9606</identifier><identifier>EISSN: 1089-7690</identifier><identifier>DOI: 10.1063/1.446709</identifier><language>eng</language><ispartof>The Journal of chemical physics, 1984-06, Vol.80 (12), p.6095-6098</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c729-30d2ca8f4f9598d8a03b7fb7b38e180ba18b72162d59e137ecf9d22f71cc5d393</citedby><cites>FETCH-LOGICAL-c729-30d2ca8f4f9598d8a03b7fb7b38e180ba18b72162d59e137ecf9d22f71cc5d393</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Ferguson, E. E.</creatorcontrib><creatorcontrib>Adams, N. 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The NO+ result establishes that the efficient quenching of NO+(v=1) by N2 is not a resonant V→V process as was previously assumed.</description><issn>0021-9606</issn><issn>1089-7690</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1984</creationdate><recordtype>article</recordtype><recordid>eNotkM1KAzEURoMoWKvgI9xlS5l6bzKdJAsXIv5haUG6HzKZGx1pZyQJhb69lHb1cfjgLI4Q94Rzwko90LwsK432QowIjS10ZfFSjBAlFbbC6lrcpPSLiKRlORL5y2UGP3AIne-4zwlcBoUInxCGCPmHYd810eVu6N0WuOf4fYAcXZ8CR4js_PFKEOKwg5WcwB4eaQp5gPXsRDgF17ewWs_OeCuugtsmvjvvWGxeXzbP78Vy_fbx_LQsvJa2UNhK70wog11Y0xqHqtGh0Y0yTAYbR6bRkirZLiyT0uyDbaUMmrxftMqqsZictD4OKUUO9V_sdi4easL6GKum-hRL_QMJq1el</recordid><startdate>19840615</startdate><enddate>19840615</enddate><creator>Ferguson, E. E.</creator><creator>Adams, N. 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G.</creatorcontrib><creatorcontrib>Smith, D.</creatorcontrib><creatorcontrib>Alge, E.</creatorcontrib><collection>CrossRef</collection><jtitle>The Journal of chemical physics</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ferguson, E. E.</au><au>Adams, N. G.</au><au>Smith, D.</au><au>Alge, E.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Rate coefficients at 300 K for the vibrational energy transfer reactions from N2( v =1) to O+2( v =0) and NO+( v =0)</atitle><jtitle>The Journal of chemical physics</jtitle><date>1984-06-15</date><risdate>1984</risdate><volume>80</volume><issue>12</issue><spage>6095</spage><epage>6098</epage><pages>6095-6098</pages><issn>0021-9606</issn><eissn>1089-7690</eissn><abstract>Rate coefficients for the reactions N2(v=1)+O+2 (v=0)→N2(v=0)+O+2 (v=1) and N2(v=1)+NO+(v=0)→N2(v=0)+NO+(v=1) have been measured in a SIFT/flowing afterglow system at 300 K, the first measurements of thermal energy vibrational transfer from neutrals to ions. The values are k=1×10−12 and <10−13 cm3 s−1, respectively. These values are consistent with an intermediate complex vibrational predissociation model which has been successful in rationalizing earlier ion vibrational relaxations by neutral collisions. The NO+ result establishes that the efficient quenching of NO+(v=1) by N2 is not a resonant V→V process as was previously assumed.</abstract><doi>10.1063/1.446709</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0021-9606 |
| ispartof | The Journal of chemical physics, 1984-06, Vol.80 (12), p.6095-6098 |
| issn | 0021-9606 1089-7690 |
| language | eng |
| recordid | cdi_crossref_primary_10_1063_1_446709 |
| source | AIP Digital Archive |
| title | Rate coefficients at 300 K for the vibrational energy transfer reactions from N2( v =1) to O+2( v =0) and NO+( v =0) |
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