Rate coefficients at 300 K for the vibrational energy transfer reactions from N2( v =1) to O+2( v =0) and NO+( v =0)

Rate coefficients at 300 K for the vibrational energy transfer reactions from N2( v =1) to O+2( v =0) and NO+( v =0)

Rate coefficients for the reactions N2(v=1)+O+2 (v=0)→N2(v=0)+O+2 (v=1) and N2(v=1)+NO+(v=0)→N2(v=0)+NO+(v=1) have been measured in a SIFT/flowing afterglow system at 300 K, the first measurements of thermal energy vibrational transfer from neutrals to ions. The values are k=1×10−12 and

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Veröffentlicht in:The Journal of chemical physics 1984-06, Vol.80 (12), p.6095-6098
Hauptverfasser: Ferguson, E. E., Adams, N. G., Smith, D., Alge, E.
Format: Artikel
Sprache:eng
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Zusammenfassung:Rate coefficients for the reactions N2(v=1)+O+2 (v=0)→N2(v=0)+O+2 (v=1) and N2(v=1)+NO+(v=0)→N2(v=0)+NO+(v=1) have been measured in a SIFT/flowing afterglow system at 300 K, the first measurements of thermal energy vibrational transfer from neutrals to ions. The values are k=1×10−12 and
ISSN:0021-9606
1089-7690
DOI:10.1063/1.446709