Divalent rhodium hexacyanide in KCl host lattice: An ESR study

The [Rg(CN)6]4− paramagnetic species is unambiguously identified by electron spin resonance spectroscopy. This species is produced when KCl single crystals doped with small amounts of K3Rh(CN)6 are submitted to 2 MeV electron irradiation at 77 K. The existence of an asymmetrical localized phonon mod...

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Veröffentlicht in:	J. Chem. Phys.; (United States) 1983-02, Vol.78 (4), p.2099-2100
Hauptverfasser:	Vugman, N. V., Franco, W. O.
Format:	Artikel
Sprache:	eng
Schlagworte:	400600 - Radiation Chemistry ALKALI METAL COMPOUNDS BEAMS CHEMICAL RADIATION EFFECTS CHEMICAL REACTIONS CHEMISTRY CHLORIDES CHLORINE COMPOUNDS CRYSTALS CYANIDES DECOMPOSITION ELECTRON BEAMS ELECTRON SPIN RESONANCE ENERGY RANGE HALIDES HALOGEN COMPOUNDS LEPTON BEAMS MAGNETIC RESONANCE MEV RANGE MEV RANGE 01-10 MONOCRYSTALS PARTICLE BEAMS POTASSIUM CHLORIDES POTASSIUM COMPOUNDS RADIATION CHEMISTRY RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY RADIATION EFFECTS RADIOLYSIS RESONANCE RHODIUM COMPOUNDS TRANSITION ELEMENT COMPOUNDS
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Beschreibung
Zusammenfassung:	The [Rg(CN)6]4− paramagnetic species is unambiguously identified by electron spin resonance spectroscopy. This species is produced when KCl single crystals doped with small amounts of K3Rh(CN)6 are submitted to 2 MeV electron irradiation at 77 K. The existence of an asymmetrical localized phonon mode is postulated in order to explain the temperature dependence of the measured spin Hamiltonian parameters.
ISSN:	0021-9606 1089-7690
DOI:	10.1063/1.444923