Off-energy-shell effects in energy sudden factorization relations: Computational study of He+H2 rotational–vibrational scattering

Off-energy-shell effects in energy sudden factorization relations: Computational study of He+H2 rotational–vibrational scattering

We apply an approximate off-shell version of the ES scaling developed for molecule–surface scattering by Gerber, Beard, and Kouri to the He+H2 CC cross section results of Flower and Kirkpatrick. The predicted results are in much better agreement with CC values than are those obtained using earlier o...

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Veröffentlicht in:The Journal of chemical physics 1983-01, Vol.78 (1), p.220-223
Hauptverfasser: Beard, L. H., Kouri, D. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:We apply an approximate off-shell version of the ES scaling developed for molecule–surface scattering by Gerber, Beard, and Kouri to the He+H2 CC cross section results of Flower and Kirkpatrick. The predicted results are in much better agreement with CC values than are those obtained using earlier on-shell versions of the ES scaling.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.444543