Excluded volume effects for branched polymers: Monte Carlo results
As a simple model of randomly branched polymers, we consider the different ways that N-bond trees may be self-avoidingly embedded on a lattice. A general Monte Carlo approach is developed and applied. The mean square radii of gyration of the conformations with a given N are found to vary with N as N...
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Veröffentlicht in: | The Journal of chemical physics 1981-11, Vol.75 (10), p.5190-5193 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | As a simple model of randomly branched polymers, we consider the different ways that N-bond trees may be self-avoidingly embedded on a lattice. A general Monte Carlo approach is developed and applied. The mean square radii of gyration of the conformations with a given N are found to vary with N as Nν, where ν?1.23 and ν?0.92 in two and three dimensions. The critical importance of volume exclusion for branched structures is discussed. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.441870 |