Excluded volume effects for branched polymers: Monte Carlo results

As a simple model of randomly branched polymers, we consider the different ways that N-bond trees may be self-avoidingly embedded on a lattice. A general Monte Carlo approach is developed and applied. The mean square radii of gyration of the conformations with a given N are found to vary with N as N...

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Veröffentlicht in:The Journal of chemical physics 1981-11, Vol.75 (10), p.5190-5193
Hauptverfasser: Seitz, W. A., Klein, D. J.
Format: Artikel
Sprache:eng
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Zusammenfassung:As a simple model of randomly branched polymers, we consider the different ways that N-bond trees may be self-avoidingly embedded on a lattice. A general Monte Carlo approach is developed and applied. The mean square radii of gyration of the conformations with a given N are found to vary with N as Nν, where ν?1.23 and ν?0.92 in two and three dimensions. The critical importance of volume exclusion for branched structures is discussed.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.441870