Solvation forces in simple dense fluids. II. Effect of chemical potential

The grand canonical ensemble Monte Carlo method is used to calculate the distribution of liquid molecules and the solvation force between two parallel solid surfaces separated by a simple liquid. Neither this distribution nor the solvation force are very sensitive to changes in the chemical potentia...

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Veröffentlicht in:	J. Chem. Phys.; (United States) 1981-01, Vol.74 (2), p.1409-1411
Hauptverfasser:	van Megen, W. J., Snook, I. K.
Format:	Artikel
Sprache:	eng
Schlagworte:	CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY ENERGY FLUIDS INTERMOLECULAR FORCES MECHANICS MONTE CARLO METHOD PHYSICAL PROPERTIES 640420 > Fluid Physics-- Properties & Structure of Fluids-- (-1987) POTENTIAL ENERGY SIMULATION SOLVATION STATISTICAL MECHANICS THERMODYNAMIC PROPERTIES
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Beschreibung
Zusammenfassung:	The grand canonical ensemble Monte Carlo method is used to calculate the distribution of liquid molecules and the solvation force between two parallel solid surfaces separated by a simple liquid. Neither this distribution nor the solvation force are very sensitive to changes in the chemical potential (i.e., bulk density) of the interstitial liquid.
ISSN:	0021-9606 1089-7690
DOI:	10.1063/1.441205