Flow-drift tube investigation of some Ar++ reactions

Flow-drift tube investigation of some Ar++ reactions

A new flow–drift technique for the investigation of ion–molecule reactions in the near thermal range, somewhat similar to the NOAA flow drift technique, is presented. Data on Ar+ reactions with H2, O2 and CO2 obtained to check the system agree well with recent NOAA results. The investigations of the...

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Veröffentlicht in:The Journal of chemical physics 1977-10, Vol.67 (8), p.3495-3499
Hauptverfasser: Lindinger, W., Alge, E., Störi, H., Pahl, M., Varney, R. N.
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container_end_page 3499
container_issue 8
container_start_page 3495
container_title The Journal of chemical physics
container_volume 67
creator Lindinger, W.
Alge, E.
Störi, H.
Pahl, M.
Varney, R. N.
description A new flow–drift technique for the investigation of ion–molecule reactions in the near thermal range, somewhat similar to the NOAA flow drift technique, is presented. Data on Ar+ reactions with H2, O2 and CO2 obtained to check the system agree well with recent NOAA results. The investigations of the first reactions of Ar++ with O2, CO2, and C2H2 show single charge transfers to be the only existing reaction channels, capture of two electrons by the Ar++ not being observed to occur. By contrast H2 showed no sign of reacting at all with Ar++ at rates within the range of these measurements.
doi_str_mv 10.1063/1.435346
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title Flow-drift tube investigation of some Ar++ reactions
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