Photoionization quantum yields. A convenient 147 nm actinometer
The photoionization quantum yields of trimethylamine, triethylamine, dipropylamine, di−iso−propylamine, and tetramethylene sulfide have been determined, at 147 nm, to be 0.38, 0.46, 0.096, 0.15, and 0.10, respectively. These ionization efficiences permit actinometry based upon saturation current mea...
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Veröffentlicht in: | The Journal of chemical physics 1975-01, Vol.62 (4), p.1469-1472 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The photoionization quantum yields of trimethylamine, triethylamine, dipropylamine, di−iso−propylamine, and tetramethylene sulfide have been determined, at 147 nm, to be 0.38, 0.46, 0.096, 0.15, and 0.10, respectively. These ionization efficiences permit actinometry based upon saturation current measurements. This physical technique of absolute photon flux measurement is contrasted with the chemical actinometers currently in use at 147 nm. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.430607 |