Spectrum of vanadium in rare gas matrices

Spectrum of vanadium in rare gas matrices

The spectrum of V isolated in Ar and Kr matrices at 10°K has been correlated with the gas phase spectrum. The electron configuration was found to be a major factor in determining the direction and the magnitude of the matrix shift for this system. A model calculation was performed using extended Hüc...

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Bibliographische Detailangaben
Veröffentlicht in:J. Chem. Phys.; (United States) 1975-01, Vol.62 (2), p.520-524
1. Verfasser: De Vore, T. C.
Format: Artikel
Sprache:eng
Schlagworte:
400201 - Chemical & Physicochemical Properties
ABSORPTION SPECTRA
ARGON
ELEMENTS
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
KRYPTON
MATRICES
METALS
NONMETALS
RARE GASES
SPECTRA
TRANSITION ELEMENTS
ULTRALOW TEMPERATURE
VANADIUM
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Beschreibung
Zusammenfassung:The spectrum of V isolated in Ar and Kr matrices at 10°K has been correlated with the gas phase spectrum. The electron configuration was found to be a major factor in determining the direction and the magnitude of the matrix shift for this system. A model calculation was performed using extended Hückel theory. A plausible explanation for the origin of the matrix shifts and the altered intensity relationships observed in the matrix has been developed.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.430506