Crystal structure of acicular γ-Fe2O3 particles used in recording media

γ-Fe2O3 particles have been examined by convergent beam electron diffraction to determine the crystal symmetry. The particles have a primitive lattice with an m3m point group and a cubic superstructure with lattice parameter approximately equal to three times the lattice parameter of the magnetite s...

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Veröffentlicht in:Journal of applied physics 1986-03, Vol.59 (5), p.1606-1610
Hauptverfasser: HUEI-MIN HO, GOO, E, THOMAS, G
Format: Artikel
Sprache:eng
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Zusammenfassung:γ-Fe2O3 particles have been examined by convergent beam electron diffraction to determine the crystal symmetry. The particles have a primitive lattice with an m3m point group and a cubic superstructure with lattice parameter approximately equal to three times the lattice parameter of the magnetite structure. This superlattice is a result of cation vacancy ordering. During observation, disordering in the electron microscope occurs and is believed to be caused by electron radiation-enhanced diffusion.
ISSN:0021-8979
1089-7550
DOI:10.1063/1.336471