Memory characteristics of cobalt-silicide nanocrystals embedded in HfO2 gate oxide for nonvolatile nanocrystal flash devices

Cobalt-silicide ( Co Si 2 ) nanocrystals (NCs) were investigated for use in charge storage for metal oxide semiconductor (MOS) devices with thin Hf O 2 tunneling and control oxide layers. Co Si 2 NCs were synthesized by exposure of Co ∕ Si ∕ Hf O 2 tunneling oxide/Si stacks to an external UV laser....

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Veröffentlicht in:Applied physics letters 2008-01, Vol.92 (1), p.013512-013512-3
Hauptverfasser: Kim, JooHyung, Yang, JungYup, Lee, JunSeok, Hong, JinPyo
Format: Artikel
Sprache:eng
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Zusammenfassung:Cobalt-silicide ( Co Si 2 ) nanocrystals (NCs) were investigated for use in charge storage for metal oxide semiconductor (MOS) devices with thin Hf O 2 tunneling and control oxide layers. Co Si 2 NCs were synthesized by exposure of Co ∕ Si ∕ Hf O 2 tunneling oxide/Si stacks to an external UV laser. Observations from transmission electron microscopy and x-ray photoelectron spectroscopy clearly confirm the formation of Co Si 2 NCs and the values of Co-Si bonding energies that are shifted 0.3 eV from original values, respectively. The Co Si 2 NCs in MOS devices exhibited a large memory window of 3.4 V as well as efficient programming/erasing speeds, good retention, and endurance times.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.2831667