Bright white upconversion luminescence in rare-earth-ion-doped Y2O3 nanocrystals

Room temperature bright white upconversion (UC) luminescence in Yb3+–Tm3+–Er3+ ions doped Y2O3 nanocrystals was obtained under single-wavelength diode laser excitation of 976nm. The white light consists of the blue, green, and red UC radiations which correspond to the transitions G41→H63 of Tm3+, H1...

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Veröffentlicht in:Applied physics letters 2007-09, Vol.91 (13)
Hauptverfasser: Chen, G. Y., Liu, Y., Zhang, Y. G., Somesfalean, G., Zhang, Z. G., Sun, Q., Wang, F. P.
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Sprache:eng
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Zusammenfassung:Room temperature bright white upconversion (UC) luminescence in Yb3+–Tm3+–Er3+ ions doped Y2O3 nanocrystals was obtained under single-wavelength diode laser excitation of 976nm. The white light consists of the blue, green, and red UC radiations which correspond to the transitions G41→H63 of Tm3+, H11∕22∕S3∕24→I15∕24, and F9∕24→I15∕24 of Er3+ ions, respectively. The UC mechanisms were proposed based on spectral, kinetic, and pump power dependence analyses. The calculated color coordinates display that white light can be achieved in a wide range of pumping powers, which promises their potential applications in the field of displays, lasers, photonics, and biomedicine.
ISSN:0003-6951
1077-3118
DOI:10.1063/1.2787893