Comparison of valence band x-ray photoelectron spectrum between Al–N-codoped and N-doped ZnO films

The valence band structures of Al–N-codoped [ZnO:(Al, N)] and N-doped (ZnO:N) ZnO films were studied by normal and soft x-ray photoelectron spectroscopy. The valence-band maximum of ZnO:(Al, N) shifts up to Fermi energy level by about 300 meV compared with that of ZnO:N. Such a shift can be attribut...

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Veröffentlicht in:Applied physics letters 2006-02, Vol.88 (6)
Hauptverfasser: Cong, G. W., Peng, W. Q., Wei, H. Y., Han, X. X., Wu, J. J., Liu, X. L., Zhu, Q. S., Wang, Z. G., Lu, J. G., Ye, Z. Z., Zhu, L. P., Qian, H. J., Su, R., Hong, C. H., Zhong, J., Ibrahim, K., Hu, T. D.
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container_issue 6
container_start_page
container_title Applied physics letters
container_volume 88
creator Cong, G. W.
Peng, W. Q.
Wei, H. Y.
Han, X. X.
Wu, J. J.
Liu, X. L.
Zhu, Q. S.
Wang, Z. G.
Lu, J. G.
Ye, Z. Z.
Zhu, L. P.
Qian, H. J.
Su, R.
Hong, C. H.
Zhong, J.
Ibrahim, K.
Hu, T. D.
description The valence band structures of Al–N-codoped [ZnO:(Al, N)] and N-doped (ZnO:N) ZnO films were studied by normal and soft x-ray photoelectron spectroscopy. The valence-band maximum of ZnO:(Al, N) shifts up to Fermi energy level by about 300 meV compared with that of ZnO:N. Such a shift can be attributed to the existence of a kind of Al–N in ZnO:(Al, N), as supported by core level XPS spectra and comparison of modified Auger parameters. Al–N increased the relative quantity of Zn–N in ZnO:(Al, N), while N–N decreased that of Zn–N in ZnO:N.
doi_str_mv 10.1063/1.2171804
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title Comparison of valence band x-ray photoelectron spectrum between Al–N-codoped and N-doped ZnO films
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