Flash Photolysis of Propane
The flash photolysis of propane has been studied at an average wavelength of 1590 Å and a pressure of 50 torr, with absorbed light intensities between 2 and 15×1021 photons/liter·sec. The primary processes, C3H8+hν→H2+C3H6(~94%),C3H8+hν→CH4+C2H4 (~6%),appear to be virtually the only reactions occurr...
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| Veröffentlicht in: | The Journal of chemical physics 1967-05, Vol.46 (10), p.3913-3915 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The flash photolysis of propane has been studied at an average wavelength of 1590 Å and a pressure of 50 torr, with absorbed light intensities between 2 and 15×1021 photons/liter·sec. The primary processes, C3H8+hν→H2+C3H6(~94%),C3H8+hν→CH4+C2H4 (~6%),appear to be virtually the only reactions occurring at low conversion. With increasing conversion, photolysis of propylene becomes important, yielding a variety of secondary products. These observations are compared with earlier studies made at low intensity and shorter wavelengths. |
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| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.1840463 |