Infrared and Raman Spectra of Methylhydrazine and Symmetrical Dimethylhydrazine

Infrared and Raman Spectra of Methylhydrazine and Symmetrical Dimethylhydrazine

Raman spectra for liquid methylhydrazine and sym-dimethylhydrazine, and infrared spectra for both liquid and vapor methylhydrazine and sym-dimethylhydrazine in the region 1600–650 cm−1 have been obtained. Frequency assignments are proposed for methylhydrazine and sym-dimethylhydrazine. The strong po...

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Veröffentlicht in:The Journal of chemical physics 1951-06, Vol.19 (6), p.704-707
Hauptverfasser: Axford, D. W. E., Janz, G. J., Russell, K. E.
Format: Artikel
Sprache:eng
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Zusammenfassung:Raman spectra for liquid methylhydrazine and sym-dimethylhydrazine, and infrared spectra for both liquid and vapor methylhydrazine and sym-dimethylhydrazine in the region 1600–650 cm−1 have been obtained. Frequency assignments are proposed for methylhydrazine and sym-dimethylhydrazine. The strong polarization of the Rayleigh scattering from these two compounds is explained on the basis of associated structures of approximately spherical symmetry.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1748336