Chemical Equilibrium in Complex Mixtures

A new method for the determination of the equilibrium composition of complex mixtures is described. The general method, which is based on the minimization of free energy, states the problem with unusual simplicity, avoiding many of the usual difficulties of description and computation. Two specific...

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Veröffentlicht in:The Journal of chemical physics 1958-05, Vol.28 (5), p.751-755
Hauptverfasser: White, W. B., Johnson, S. M., Dantzig, G. B.
Format: Artikel
Sprache:eng
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Zusammenfassung:A new method for the determination of the equilibrium composition of complex mixtures is described. The general method, which is based on the minimization of free energy, states the problem with unusual simplicity, avoiding many of the usual difficulties of description and computation. Two specific computation procedures are shown, one using a steepest descent technique applied to a quadratic fit, the other making use of linear programing.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1744264