The Szilard-Chalmers Reaction in Aqueous Solutions of Tri- and Hexavalent Chromium

Szilard-Chalmers (nuclear recoil) reactions have been observed in aqueous solutions of tri- and hexavalent chromium. The effects of pH, concentration, and a number of other variables have been examined, and the retention is found to depend on several of these factors. The results are interpreted in...

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Veröffentlicht in:The Journal of chemical physics 1954-06, Vol.22 (6), p.1088-1093
Hauptverfasser: Fishman, Lawrence M., Harbottle, Garman
Format: Artikel
Sprache:eng
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Zusammenfassung:Szilard-Chalmers (nuclear recoil) reactions have been observed in aqueous solutions of tri- and hexavalent chromium. The effects of pH, concentration, and a number of other variables have been examined, and the retention is found to depend on several of these factors. The results are interpreted in terms of thermal oxidation-reduction and exchange reactions of chromium V and/or IV.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1740270