Sedimentation in Chemically Reacting Systems. II. Numerical Calculations for Dimerization

Results are given for some numerical calculations, carried out on a high-speed computer, for a simple model of sedimentation with concurrent dimerization. These results show that in a simple, dimerizing system anywhere from one to three concentration-gradient peaks may be simultaneously observable....

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Veröffentlicht in:The Journal of chemical physics 1962-11, Vol.37 (9), p.1926-1932
Hauptverfasser: Belford, Geneva G., Belford, R. Linn
Format: Artikel
Sprache:eng
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Zusammenfassung:Results are given for some numerical calculations, carried out on a high-speed computer, for a simple model of sedimentation with concurrent dimerization. These results show that in a simple, dimerizing system anywhere from one to three concentration-gradient peaks may be simultaneously observable. The numerical techniques used involved some interesting aspects in themselves and are therefore discussed briefly. Finally, a simple analytic expression for theoretical concentration-gradient peak decay rates is presented.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1733407