Paramagnetic Resonance of Glassy Mn(H2O)62

The ESR absorption curve for the Mn2+ ion in an aqueous glass is structureless and almost symmetrical, with a width of 800 Oe between inflections. The theory of the Mn2+ spectrum in a single crystal with tetragonal symmetry can be related to this result by averaging over random orientations and choo...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1962-12, Vol.37 (12), p.3000-3002
Hauptverfasser: Wakim, Fahd G., Nolle, A. W.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The ESR absorption curve for the Mn2+ ion in an aqueous glass is structureless and almost symmetrical, with a width of 800 Oe between inflections. The theory of the Mn2+ spectrum in a single crystal with tetragonal symmetry can be related to this result by averaging over random orientations and choosing the value 300 Oe for the axial splitting parameter D.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1733132