VCl4 Vapor Spectrum and Jahn-Teller Splitting
The absorption spectrum of VCl4 vapor from 400 to 23 000 cm—1 was determined. A system of bands with maximum absorption coefficient at 9000 cm—1 is attributed to ligand field splitting of the 2D ground term of the free V (V) ion. The three-component structure of this band is attributed to Jahn-Telle...
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| Veröffentlicht in: | The Journal of chemical physics 1962-01, Vol.36 (3), p.633-639 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The absorption spectrum of VCl4 vapor from 400 to 23 000 cm—1 was determined. A system of bands with maximum absorption coefficient at 9000 cm—1 is attributed to ligand field splitting of the 2D ground term of the free V (V) ion. The three-component structure of this band is attributed to Jahn-Teller splitting of the excited state. Simple calculations of the expected splitting are offered in support of this assignment. |
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| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.1732585 |