The Differences in the Vapor Pressures and Entropies of the Liquid Nitrogens

The Differences in the Vapor Pressures and Entropies of the Liquid Nitrogens

The differences in the thermodynamic properties of liquid nitrogen (14) and liquid nitrogen (15) are discussed on the basis of several Debye-like models. The quantum mechanical effects are found to be greater than one could expect from an harmonic oscillator model. Other factors affecting these prop...

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Veröffentlicht in:The Journal of chemical physics 1942-12, Vol.10 (12), p.717-730
1. Verfasser: Kirshenbaum, Isidor
Format: Artikel
Sprache:eng
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Zusammenfassung:The differences in the thermodynamic properties of liquid nitrogen (14) and liquid nitrogen (15) are discussed on the basis of several Debye-like models. The quantum mechanical effects are found to be greater than one could expect from an harmonic oscillator model. Other factors affecting these properties are considered.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1723653