Paramagnetic Resonance Study of NO2 in Irradiated KNO3 at 4°K

The paramagnetic resonance spectrum of NO2 has been studied at 4°K in gamma-irradiated single crystals of KNO3. The g and hyperfine parameters are essentially the same as those for NO2 in NaNO2 but substantially different than those in KNO3 at 77°K, indicating that thermal motion at 77°K is frozen o...

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Veröffentlicht in:The Journal of chemical physics 1967-10, Vol.47 (8), p.2552-2554
Hauptverfasser: Holmberg, Robert W., Livingston, Ralph
Format: Artikel
Sprache:eng ; jpn
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Zusammenfassung:The paramagnetic resonance spectrum of NO2 has been studied at 4°K in gamma-irradiated single crystals of KNO3. The g and hyperfine parameters are essentially the same as those for NO2 in NaNO2 but substantially different than those in KNO3 at 77°K, indicating that thermal motion at 77°K is frozen out at the lower temperature.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1712267