Tracer Diffusion and Shear Viscosity for the System Isobutyric Acid–Water near the Critical Mixing Point

Tracer diffusion coefficients of 14C isobutyric acid in mixtures of isobutyric acid–water have been measured over the entire concentration range at ε = 3.9 × 10−4 above the critical point using the diaphragm cell technique. No anomaly was detected. The temperature dependence of the shear viscosity c...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:The Journal of chemical physics 1971-08, Vol.55 (4), p.1716-1720
Hauptverfasser: Allegra, Joseph C., Stein, Arnold, Allen, Guy F.
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Tracer diffusion coefficients of 14C isobutyric acid in mixtures of isobutyric acid–water have been measured over the entire concentration range at ε = 3.9 × 10−4 above the critical point using the diaphragm cell technique. No anomaly was detected. The temperature dependence of the shear viscosity coefficient for mixtures of critical composition was determined over the temperature range 6.7 × 10−6 
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1676301