Isoelectronic Molecules. II. First- and Second-Order Physical Properties
It has been shown that first- and second-order physical properties of isoelectronic molecules are interrelated in a simple way. This follows from the fact that the corresponding first- and second-order operators are homogeneous functions of position and nuclear charge. The results are rigorously tru...
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Veröffentlicht in: | The Journal of chemical physics 1970-07, Vol.53 (2), p.579-582 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | It has been shown that first- and second-order physical properties of isoelectronic molecules are interrelated in a simple way. This follows from the fact that the corresponding first- and second-order operators are homogeneous functions of position and nuclear charge. The results are rigorously true for noninteracting electrons and can be extended to include interelectronic effects as well. |
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ISSN: | 0021-9606 1089-7690 |
DOI: | 10.1063/1.1674030 |