Isoelectronic Molecules. II. First- and Second-Order Physical Properties

It has been shown that first- and second-order physical properties of isoelectronic molecules are interrelated in a simple way. This follows from the fact that the corresponding first- and second-order operators are homogeneous functions of position and nuclear charge. The results are rigorously tru...

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Veröffentlicht in:The Journal of chemical physics 1970-07, Vol.53 (2), p.579-582
Hauptverfasser: Laurenzi, Bernard J., Saturno, Antony F.
Format: Artikel
Sprache:eng
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Zusammenfassung:It has been shown that first- and second-order physical properties of isoelectronic molecules are interrelated in a simple way. This follows from the fact that the corresponding first- and second-order operators are homogeneous functions of position and nuclear charge. The results are rigorously true for noninteracting electrons and can be extended to include interelectronic effects as well.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1674030