Variational Principles from the Schwarz Inequality

The Schwarz inequality is used to generate variational principles for evaluating perturbation sums. By constructing two suitable kets and applying Schwarz's inequality to them, a bound results which contains an arbitrary (variational) operator. The method is illustrated with reference to a fami...

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Veröffentlicht in:J. Chem. Phys. 52: 1920-2(15 Feb 1970) 1970-01, Vol.52 (4), p.1920-1922
Hauptverfasser: Kim, Chin Hyung, Kern, C. William
Format: Artikel
Sprache:eng
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Zusammenfassung:The Schwarz inequality is used to generate variational principles for evaluating perturbation sums. By constructing two suitable kets and applying Schwarz's inequality to them, a bound results which contains an arbitrary (variational) operator. The method is illustrated with reference to a family of frequency-dependent sums for which the corresponding bound is shown to be a generalized form of Hylleraas's variation–perturbation principle. It is also pointed out that the Schwarz inequality provides bounds on simple matrix elements.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1673233