Reduced Spin–Spin Matrix Elements for f4

Reduced Spin–Spin Matrix Elements for f4

Reduced matrix elements for all possible two-body Hermitian operators with spin and orbital rank of two are evaluated for the f4 configuration. Most of the vanishing matrix elements can be explained by simple group-theoretical selection rules and some can be explained by vanishing coupling coefficie...

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Veröffentlicht in:The Journal of chemical physics 1969-11, Vol.51 (9), p.3789-3794
Hauptverfasser: Armstrong, Lloyd, Taylor, Lyle H.
Format: Artikel
Sprache:eng
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Zusammenfassung:Reduced matrix elements for all possible two-body Hermitian operators with spin and orbital rank of two are evaluated for the f4 configuration. Most of the vanishing matrix elements can be explained by simple group-theoretical selection rules and some can be explained by vanishing coupling coefficients. However, 16 zeros still remain to be explained.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1672593