Spectroscopic Closure Property and Franck–Condon Band Structuring
A relationship is derived from evaluating the change in molecular equilibrium size on excitation from a moment analysis of the electronic spectrum. The method is applied to the Lb1←A1 benzene spectrum. The agreement of the calculated bond lengthening with that derived from independent rotational ana...
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| Veröffentlicht in: | The Journal of chemical physics 1969-01, Vol.50 (10), p.4558-4560 |
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| Hauptverfasser: | , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | A relationship is derived from evaluating the change in molecular equilibrium size on excitation from a moment analysis of the electronic spectrum. The method is applied to the Lb1←A1 benzene spectrum. The agreement of the calculated bond lengthening with that derived from independent rotational analysis would seem to confirm the adequacy of a spectroscopic closure property for benzene. |
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| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.1670930 |