Charge Transfer of N2+, O2+, and NO+ to Sodium Atoms at Thermal Energies

Charge Transfer of N2+, O2+, and NO+ to Sodium Atoms at Thermal Energies

A steady-state flowing afterglow system has been utilized to measure the two-body rate coefficients for the charge-transfer reactions of N2+, O2+, and NO+ to sodium atoms. The reactions of N2+ and O2+ are rapid with rate coefficients of approximately 5.8 and 6.7 × 10−10 cm3/sec, respectively, wherea...

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Veröffentlicht in:The Journal of chemical physics 1969-01, Vol.50 (1), p.287-293
Hauptverfasser: Farragher, A. L., Peden, J. A., Fite, W. L.
Format: Artikel
Sprache:eng
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Zusammenfassung:A steady-state flowing afterglow system has been utilized to measure the two-body rate coefficients for the charge-transfer reactions of N2+, O2+, and NO+ to sodium atoms. The reactions of N2+ and O2+ are rapid with rate coefficients of approximately 5.8 and 6.7 × 10−10 cm3/sec, respectively, whereas the NO+ reaction is found to be an order of magnitude slower.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1670790