Asymptotic Behavior of the Light-Scattering Function of Coiled Molecules

This paper discusses the asymptotic solution of the scattering function P(θ) for large x, where x is proportional to the scattering angle, radius of gyration, and the wavenumber. The theoretical model employed for the calculation of the P(θ)-vs-x curves was presented in the preceding paper. The resu...

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Veröffentlicht in:The Journal of chemical physics 1968-10, Vol.49 (7), p.2896-2904
Hauptverfasser: Mazur, J., McIntyre, D., Wims, A. M.
Format: Artikel
Sprache:eng
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Zusammenfassung:This paper discusses the asymptotic solution of the scattering function P(θ) for large x, where x is proportional to the scattering angle, radius of gyration, and the wavenumber. The theoretical model employed for the calculation of the P(θ)-vs-x curves was presented in the preceding paper. The results are discussed with respect to the experimental data, after the results for P(θ) are corrected for various values of polydispersity. A general analysis of the theoretical P(θ)-vs-x curves is presented, and the effect of the shape of the chain-end distribution function on the asymptotic behavior of the light-scattering function is discussed.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1670524