Fluorescence detected microwave Stark effect measurements in excited vibrational states of H2CO

Fluorescence detected microwave Stark effect measurements in excited vibrational states of H2CO

We describe a microwave-optical double resonance experiment designed for Stark effect measurements on molecules in excited vibrational energy levels of ground electronic states. This technique, which employs pulsed laser excitation and laser induced fluorescence detection, has been used to measure e...

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Veröffentlicht in:The Journal of chemical physics 2003-11, Vol.119 (17), p.8910-8915
Hauptverfasser: Theulé, Patrice, Callegari, Andrea, Rizzo, Thomas R., Muenter, J. S.
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container_end_page 8915
container_issue 17
container_start_page 8910
container_title The Journal of chemical physics
container_volume 119
creator Theulé, Patrice
Callegari, Andrea
Rizzo, Thomas R.
Muenter, J. S.
description We describe a microwave-optical double resonance experiment designed for Stark effect measurements on molecules in excited vibrational energy levels of ground electronic states. This technique, which employs pulsed laser excitation and laser induced fluorescence detection, has been used to measure electric dipole moments in the 11, 51, and 52 vibrational states of formaldehyde. In addition, a Stark induced quantum beat experiment is briefly described.
doi_str_mv 10.1063/1.1614771
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title Fluorescence detected microwave Stark effect measurements in excited vibrational states of H2CO
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