Fluorescence detected microwave Stark effect measurements in excited vibrational states of H2CO
We describe a microwave-optical double resonance experiment designed for Stark effect measurements on molecules in excited vibrational energy levels of ground electronic states. This technique, which employs pulsed laser excitation and laser induced fluorescence detection, has been used to measure e...
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| Veröffentlicht in: | The Journal of chemical physics 2003-11, Vol.119 (17), p.8910-8915 |
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| Hauptverfasser: | , , , |
| Format: | Artikel |
| Sprache: | eng |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | We describe a microwave-optical double resonance experiment designed for Stark effect measurements on molecules in excited vibrational energy levels of ground electronic states. This technique, which employs pulsed laser excitation and laser induced fluorescence detection, has been used to measure electric dipole moments in the 11, 51, and 52 vibrational states of formaldehyde. In addition, a Stark induced quantum beat experiment is briefly described. |
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| ISSN: | 0021-9606 1089-7690 |
| DOI: | 10.1063/1.1614771 |