The role of phase in molecular Rydberg wave packet dynamics

The dynamics of Rydberg wave packets in NO are investigated in the regime where the electronic period is comparable with the rotational motion of the molecular ion core. The presence of a rotating molecular core manifests itself in the wave packet dynamics as a series of peaks separated by the rotat...

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Veröffentlicht in:The Journal of chemical physics 2003-08, Vol.119 (6), p.3085-3091
Hauptverfasser: Smith, R. A. L., Stavros, V. G., Verlet, J. R. R., Fielding, H. H., Townsend, D., Softley, T. P.
Format: Artikel
Sprache:eng
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Zusammenfassung:The dynamics of Rydberg wave packets in NO are investigated in the regime where the electronic period is comparable with the rotational motion of the molecular ion core. The presence of a rotating molecular core manifests itself in the wave packet dynamics as a series of peaks separated by the rotational beat period TRot, but offset by ΔμTRot, where Δμ is the difference in quantum defect between the two dominant Rydberg series in the superposition. We rationalize this by treating the dynamics of a wave packet created from a coherent superposition of two interleaved Rydberg series as two separate electron wave packets, which interfere with one another when they overlap spatially. There is a periodic phase difference between the two wave packets that depends on the rotational energy of the core in each Rydberg series and also on the quantum defects. The resulting interference pattern in the Rydberg population manifests itself as peaks in the wave packet spectrum at the stroboscopic period.
ISSN:0021-9606
1089-7690
DOI:10.1063/1.1589473