Recommended Vapor–Liquid Equilibrium Data. Part 1: Binary n-Alkanol–n-Alkane Systems
The recommended vapor–liquid equilibrium (VLE) data for 39 binary n-alcohol–n-alkane systems have been obtained after critical evaluation of all data (490 data sets) reported in the open literature up to the middle of 2001. The evaluation procedure consisted in combining the thermodynamic consistenc...
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Veröffentlicht in: | Journal of physical and chemical reference data 2002-09, Vol.31 (3), p.701-748 |
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Hauptverfasser: | , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | The recommended vapor–liquid equilibrium (VLE) data for 39 binary n-alcohol–n-alkane systems have been obtained after critical evaluation of all data (490 data sets) reported in the open literature up to the middle of 2001. The evaluation procedure consisted in combining the thermodynamic consistency tests, data correlation, comparison with enthalpy of mixing data, and comparison of VLE data for various mixtures. The data were correlated with equations based on the local compositions concept as well as with the equation of state appended with a chemical term (EoSC) proposed by Góral. The recommended data are presented in the form of individual pages containing tables of data, figures, and auxiliary information. Each page corresponds to one system and contains three isotherms (spaced by at least 15 K) and one isobar (preferably at 101.32 kPa). Experimental gaps were completed with the predicted data. |
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ISSN: | 0047-2689 1529-7845 |
DOI: | 10.1063/1.1480097 |