Band lineup between CdS and ultra high vacuum-cleaved CuInS2 single crystals

The interface formation between vacuum evaporated CdS and ultrahigh vacuum-cleaved CuInS2 single crystals has been studied by synchrotron excited photoelectron spectroscopy. The valence band discontinuity is determined directly from valence band difference spectra to be ΔEV=0.6 (±0.1) eV. This value...

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Veröffentlicht in:Applied physics letters 1997-03, Vol.70 (10), p.1299-1301
Hauptverfasser: Klein, A., Löher, T., Tomm, Y., Pettenkofer, C., Jaegermann, W.
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container_issue 10
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container_title Applied physics letters
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creator Klein, A.
Löher, T.
Tomm, Y.
Pettenkofer, C.
Jaegermann, W.
description The interface formation between vacuum evaporated CdS and ultrahigh vacuum-cleaved CuInS2 single crystals has been studied by synchrotron excited photoelectron spectroscopy. The valence band discontinuity is determined directly from valence band difference spectra to be ΔEV=0.6 (±0.1) eV. This value is significantly smaller than for other preparation conditions given in the literature and evidently not suitable for solar cell applications. The similarity to observations at the CdS/CuInS2 interfaces suggests that neutrality levels play a dominant role in establishing the band lineup at interfaces containing chalcopyrite semiconductors.
doi_str_mv 10.1063/1.118517
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title Band lineup between CdS and ultra high vacuum-cleaved CuInS2 single crystals
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