Samarium(III) Triflate Catalyzed Conjugate Addition of Amines to Electron-Deficient Alkenes

Samarium(III) Triflate Catalyzed Conjugate Addition of Amines to Electron-Deficient Alkenes

Abstract Amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of samarium(III) triflate at ambient temperature to produce the corresponding β-amino compounds in excellent yields. This method is simple, convenient, and works efficiently under...

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Veröffentlicht in:Synthesis (Stuttgart) 2007-11, Vol.2007 (22), p.3447-3450
Hauptverfasser: Yadav, J. S., Reddy, A. Ramesh, Rao, Y. Gopal, Narsaiah, A. V., Reddy, B. V.
Format: Artikel
Sprache:eng
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short paper
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Zusammenfassung:Abstract Amines undergo smooth nucleophilic addition to α,β-unsaturated compounds in the presence of a catalytic amount of samarium(III) triflate at ambient temperature to produce the corresponding β-amino compounds in excellent yields. This method is simple, convenient, and works efficiently under mild conditions.
ISSN:0039-7881
1437-210X
DOI:10.1055/s-2007-990876